NIOSH Pocket Guide to Chemical Hazards

Vinyl cyclohexene dioxide CAS 106-87-6
C8H12O2 RTECS RN8640000
Synonyms & Trade Names
1-Epoxyethyl-3,4-epoxy-cyclohexane; 4-Vinylcyclohexene diepoxide; 4-Vinyl-1-cyclohexene dioxide
DOT ID & Guide
NIOSH REL: Ca TWA 10 ppm (60 mg/m3) [skin] See Appendix A
OSHA PEL†: none
IDLH Ca [N.D.] Conversion 1 ppm = 5.73 mg/m3
Physical Description
Colorless liquid.
MW: 140.2
BP: 441°F
FRZ: -164°F
Sol: High
VP: 0.1 mmHg
IP: ?

Sp.Gr: 1.10
Fl.P(oc): 230°F
UEL: ?
LEL: ?

Class IIIB Combustible Liquid: Fl.P. at or above 200°F.
Incompatibilities & Reactivities
Alcohols, amines, water [Note: Slowly hydrolyzes in water.]
Measurement Methods
None available
Personal Protection & Sanitation
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated
Remove: When wet or contaminated
Change: No recommendation
Provide: Eyewash, Quick drench
First Aid (See procedures)
Eye: Irrigate immediately
Skin: Water wash immediately
Breathing: Respiratory support
Swallow: Medical attention immediately
Respirator Recommendations NIOSH
At concentrations above the NIOSH REL, or where there is no REL, at any detectable concentration: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode/(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape: (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister/Any appropriate escape-type, self-contained breathing apparatus
Exposure Routes inhalation, skin absorption, ingestion, skin and/or eye contact
Symptoms In animals: irritation eyes, skin, respiratory system; testicular atrophy; leukopenia (reduced blood leukocytes), necrosis thymus; skin sensitization; [potential occupational carcinogen]
Target Organs Eyes, skin, respiratory system, blood, thymus, reproductive system

Cancer Site [in animals: skin tumors]