Multidisciplinary University Research Initiative 2000

Phonon Enhancement of Optoelectronic and Electronic Devices

INTRODUCTION: Motivation, Strategy, Approach and Goals

Semiconductor heterostructure devices, which exploit the concept of “bandstructure engineering”of the electronic degrees of freedom have revolutionized modern optoelectronics and offer major new opportunities for the development of the next generation of micro/nanoelectronic devices as well. Entire generations of semiconductor lasers spanning wavelength range from the infrared to the blue are one prime example of such application of heteroepitaxy that has fundamentally changed the design of these compact, efficient optical sources.

By contrast, very little attention has been given to the use of lower dimensional semiconductor and electronic material structures to exploit and control the lattice degrees of freedom in high performance devices. The importance of phonons is, of course, widely recognized, but generally in the context of performance diminishing characteristics such as increased electronic scattering due to carrier-phonon interaction. Unlike superconductivity where such interaction is fundamental to the entire phenomena and several classes of devices (SQUIDs etc), there are very few analogs in semiconductor device science, the Gunn microwave oscillator relying on phonon assisted intervalley scattering being one such rare instance. In earlier red LEDs, the use of the nitrogen isoelectronic center in GaP benefited from carrier-phonon scattering in bridging the indirect bandgap; however these LEDs have been superceded by the new generations of heterostructure light emitting devices that rely on direct electronic interband transitions.

In this MURI program we begin with the premise that extensive opportunities exist to transform the problems generally associated with phonons presenting an overhead into a distinct benefit for substantial enhancement of a broad range of optoFigure 1: Phonon enhancement in strategic heterostructure devices.electronic and electronic devices. Our explicit goal and objective is to achieve a significant improvement and major technological impact on the performance of a wide spectrum of advanced and novel semiconductor optoelectronic/electronic devices, by explicitly focusing on the role of phonon assisted and phonon dominated processes that control the functionality and applications of such devices. The devices range from quantum cascade and intersubband mid-IR lasers to new THz frequency laser sources, from semiconductor lasers in the blue and near ultraviolet to high power microwave FETs, to novel ultrahigh speed bipolar tunneling transistors. Figure 1: Key microscopic processes.  Additionally, new physical phenomena will be studied in which electron-electron interaction, crucial for ballistic and coherent electronic devices, is spectroscopically characterized via the electron-phonon interaction. We have assembled a team of experts whose research represents work at the leading edge of semiconductor device science work. The interactive team has been organized specifically to integrate a potent core of scientific expertise in phonon science, both experiment and theory in terms of the interaction of phonons with the electronic degrees of freedom in semiconductor nanostructures and high speed, high power devices. Established collaborations and scientific interactions exists within the team and coupling to leading industrial/commercial efforts is in place for technology transfer of the optoelectronic and electronic devices which define the technical mission of this proposal.

The scientific strategy for the proposed program is schematically sketched in Figure 1. The left panel shows the pivotal role of the phonon enhancement processes for the optoelectronic and electronic devices which form the technological backbone of the program. The right panel identifies the core group of microscopic physical processes for the basic science component of the program, that range from quantum well dynamics to phonon assisted intersubband depopulation effects, from phonon intermediated e-e interactions in quantum transport to ballistic phonon propagation and "coherent" thermal transport. The team will pursue two different testbed outlays in applying sophisticated experimental and theoretical tools to the problem areas identified in Fig 1. First, we will pursue the growth, synthesis, nanofabrication, and study of the types of specifically tailored lower dimensional heterostructures where the phonon enhancement issues can be systematically studied. Secondly, in close collaboration with industrial partners, we will pursue the incorporation and implementation of the phonon enhancement processes to real optolectronic and electronic device structures. Advanced experimental probes and device physics modeling will be implemented for identifying the impact of specific phonon enhancement features in the high performance devices.

Figure 2: Key semiconductor heterostructures for the team's research.The device driven projects described in this proposal involve key classes of semiconductor heterostructure and lower dimensional structures in which we seek to intersect fundamental phonon physics with both material and device design to reach new levels of phonon enhanced device performance, or to create an opportunity for an entirely new electronic device. One example of the former includes the intersubband and cascade IR lasers, an example of the latter include the interband tunneling SiGe heterojunction bipolar transistor. A summary of the principal material systems that form the core of this proposal is shown in Figure 2. The material science expertise within the team and its collaborators ensures that the highest quality epitaxially grown heterostructures are available for the projects described below. For example, the University of Houston group has extensive molecular beam epitaxial facilities for synthesis of the GaInAsSb system, while the collaboration with Lucent Technologies gives the team access to state-of-the-art Si/Ge heterostructures in a closely coupled, feedback driven mode of interactive research.

Ballistic phonon focusing in a cubic crystal.An example of another theme within the proposed research program is the study of ballistic phonon propagation in lower dimensional and anisotropic heterostructures, with the goal to create directional energy flow of lattice excitations in active electronic devices. The question of energy dissipation and lattice heating is central to most high performance, high power semiconductor optoelectronic devices. In submicron, mesoscale structures, the channeling of excess energy from the electronic degrees of freedom into the lattice forms a new paradigm, that is, the prospect of spatially directed flow of lattice energy in the form of ballistic acoustic phonons, for example. Our team possesses widely recognized expertise in the field of ballistic phonon physics that will be applied and integrated to explore the question of both thermal and nonthermal cooling of electronic excitations by anisotropic phonon energy flow. Such speculative prospects arise in the present advanced device circumstances in the spirit of e.g. the ballistic phonon focusing of Figure 3, which is computed (by Maris) as follows: One has a point source of phonons (e.g. hot electron emitter) some distance below the surface of a cubic crystal. This point source sends out phonons in all spatial directions. The figure shows how these phonons arrive at the crystal surface, taken here to be a 100 surface. Each dot in the graph corresponds to a single phonon. Longitudinal phonons are colored white, fast transverse phonons are colored blue, and the slow transverse are in red. The high intensity areas indicate directions where the group velocity is stationary with respect to changes in the wave vector direction. The "piling up" of phonons at these locations leads to the focusing effect.

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