Publications
(Peer-Reviewed Journal Articles):
38. Oakley, K.M.; Lehane, R.L; Zhao, Z.; Kim E.” Dioxygen reactivity of a biomimetic [4Fe-4S] compound exhibits [4Fe-4S] to [2Fe-2S] cluster conversion”. J. Inorg. Biochem. 2022, Doi: 10.1016/j.jinorgbio.2022.111714
37.Lehnert, N.; Kim, E.; Dong, H. T.; Harland, J. B.; Hunt, A. P.; Manickas, E. C.; Oakley, K. M.; Pham, J.; Reed, G. C.; Alfaro, V. S. “The Biologically Relevant Coordination Chemistry of Iron and Nitric Oxide: Electronic Structure and Reactivity.” Chem. Rev. 2021, 121, 14682–14905. Selected for the journal auxiliary cover
36. Oakley, K. M.; Sterling, K.; Shearer, J.; Kim, E. Controlled Protonation of [2Fe-2S] Leading to MitoNEET Analogues and Concurrent Cluster Modification. Inorg. Chem. 2021, 21, 16074–16078.
35. Arcadia, C.E.; Dombroski, A.; Oakley, K.; Chen, S. L.; Tann, H.; Rose, C.; Kim, E.; Reda, S.; Rubenstein, B.M.; Rosenstein, J.K. “Leveraging autocatalytic reactions for chemical domain image classification” Chem. Sci. 2021, 12, 5464-5472.
34. Oakley, K. M.; Zhao, Z.; Lehane, R. L.; Ma, J.; Kim E. Generation of H2S from Thiol-Dependent NO Reactivity of Model [4Fe-4S] Cluster and Roussin's Black Anion. Inorg. Chem. 2021, 21, 15910–15917.
33. Dombroski, A.; Oakley, K.; Arcadia, C.; Nourael, F.; Ling, S.; Rosenstein, J.; Reda, S.; Kim E. “Implementing parallel arithmetic via acetylation and its application to chemical image Processing” Proc. R. Soc. A. 2021, 477, 20200899
32. Arcadia, C.E.; Kennedy, E.; Geiser, J.; Dombroski, A.; Oakley, K.; Chen, S.-L.; Sprague, L.; Ozmen, M.; Sello, J.; Weber, P.M.; Reda, S.; Rose, C.; Kim, E.; Rubenstein, B. M.; Rosenstein, J. K. “Multicomponent Molecular Memory” Nature Communications, 2020, 11, 691, p1-8
31. Rosenstein, J.K.; Rose, C.; Reda, S.; Weber, P. M.; Kim, E.; Sello, J.; J. Geiser, J.; Kennedy,, E.; Arcadia, C.; Dombroski, A.; Oakley, K.; Chen,S.-L.; Tann, H.; Rubenstein, B. M. “Principles of Information Storage in Small-Molecular Mixtures” - IEEE Transactions on Nanobioscience, 2020, 19, pp378-384
30. Seo, J.; Shearer, J.; Williard, P. G.; Kim, E. “Reactivity of a biomimetic W(IV) bis-dithiolene complex with CO2 leading to formate production and structural rearrangement “ - Dalton Trans, 2019, 48, pp17441-17444
29. Arcadia, C.; Tann, H.; Dombroski, A.; Ferguson, K.; Chen, S.-L.; Kim, E.; Rose, C.; Rubenstein, B. M.; Reda, S.; Rosenstein, J. “Parallelized Linear Classification with Volumetric Chemical Perceptrons” Proceedings of the IEEE International Conference on Rebooting Computing 2018.
28. Elrod, L. T. and Kim, E.* “Lewis Acid Assisted Nitrate Reduction with Biomimetic Molybdenum Oxotransferase Complex” - Inorg. Chem, 2018, 57, pp2594-2602
27. Cao, R.; Elrod, L. T.; Lehane, R. L.; Kim, E.; Karlin, K. D.* “A Peroxynitrite Dicopper Complex: Formation via Cu–NO and Cu–O2 Intermediates and Reactivity via O–O Cleavage Chemistry” - J. Am. Chem. Soc. 2016, 138, pp16148–16158
26. Speelman, A. L.; Zhang, B.; Silakov, A.; Skodje, K. M.; Alp, E. E.; Zhao, J.; Hu, M. Y.; Kim, E.; Krebs, C.; Lehnert, N.* “Unusual Synthetic Pathway for an {Fe(NO)2}9 Dinitrosyl Iron Complex (DNIC) and Insight into DNIC Electronic Structure via Nuclear Resonance Vibrational Spectroscopy” - Inorg. Chem., 2016, 55, pp 5485–5501
25. Fitzpatrick. J. and Kim, E.* "Synthetic Modeling Chemistry of Iron-Sulfur Clusters in Nitric Oxide Signalling" - Acc. Chem. Res. 2015, 48, pp 2453-2461
24. Fitzpatrick. J. and Kim, E.* "New Synthetic Routes to Iron-Sulfur Clusters: Deciphering the Repair Chemistry of [2Fe-2S] Clusters from Mononitrosyl Iron Complexes" - Inorg. Chem. 2015, 54, pp 10559-10567.
23. Tran, C.T.; Williard, P.G.; Kim, E.* "Nitric Oxide Reactivity of [2Fe-2S] Clusters Leading to H2S Generation" - J. Am. Chem. Soc. 2014, 136 (34), pp 11874-11877
22. Fitzpatrick. J.; Kalyvas, H.; Filipovic, M.R.; Ivanović-Burmazović, I.; MacDonald, J.C.; Shearer, J.; Kim, E.* "Transformation of a Mononitrosyl Iron Complex to a [2Fe-2S] Cluster by a Cysteine Analogue" - J. Am. Chem. Soc. 2014, 136 (20), pp 7229-7232
21. Skodje, K.M.; Kwon, M-Y; Chung, S.W.; Kim, E.* "Coordination-Triggered NO Release from a Dinitrosyl Iron Complex leads to Anti-Inflammatory Activity" - Chem Sci. 2014, 5, pp 2374-2378
20. Tran, C.T.; Skodje, K.M.; Kim, E.* "Synthetic Monomeric Dinitrosyl Iron Complexes: Synthesis and Reactivity" - Progress in Inorganic Chemistry, Karlin, K.D., Ed.; Wiley:New Jersey, 2013, 58, pp 339-379
19. Seo, J.; Williard, P.G.; Kim, E.* "Deoxygenation of Mono-oxo Bis(dithiolene) Mo and W Complexes by Protonation" - Inorg. Chem. 2013, 52, pp 8706-8712.
18.Fitzpatrick, J.; Kalyvas, H.; Shearer, J.; Kim, E.* "Dioxygen mediated conversion of {Fe(NO)2}9 dinitrosyl iron complexes to Roussin's red esters" - Chem. Commun., 2013, 49, pp 5550-5552.
17. Tran, C.T. and Kim, E.* "Acid-Dependent Degradation of a [2Fe-2S] Cluster by Nitric Oxide" - Inorg. Chem., 2012, 51, pp 10086-10088.
16. Seo, J. and Kim, E.* "O-Atom Exchange between H2O and CO2 Mediated by a Bis(dithiolene)tungsten Complex" - Inorg. Chem., 2012, 51, pp 7951-7953.
15. Skodje, K.M.; Williard, P. G.; Kim, E.* "Conversion of {Fe(NO)2}10 dinitrosyl iron to nitrato iron(III) species by molecular oxygen" - Dalton Transactions, 2012, 41, pp 7849-7851.
14. Tran, N.G; Kalyvas, H.; Skodje, K.M.; Hayashi, T.; Moënne-Loccoz, P.; Callan, P.E.; Shearer, J.; Kirschenaum, L.J.; Kim. E.* "Phenol Nitration Induced by an {Fe(NO)2}10 Dinitrosyl Iron Complex" J. Am. Chem Soc., 2011, 133, pp 1184-1187.
13. Liu, C.; Kim, E.; Demple, B.; Seeman, N.C. “A DNA-Based Nanomechanical Device Used to Characterize the Distortion of DNA by Apo-SoxR Protein” Biochemistry, 2012, 51, 937-943.
12. Kim, E.; Rye, P.T.; Croy, R.G.; Essigmann, J.M. “Programmable Platinum Antitumor Agents for Ovarian and Breast Cancers” J. Inorg. Biochem., 2009, 103, 256-261.
11. Chufán, E.E.; Mondal, B.; Gandhi, T.; Kim, E.; Rubie, N; Moënne-Loccoz, P.; Karlin, K.D. “Reactivity Studies on FeIII-(O22–)-CuII Compounds: Influence of the Ligand Architecture and Copper Ligand Denticity” Inorg. Chem., 2007, 46, 6382-6394.
10. Kim, E.; Helton, M.E.; Lu, S.; Moënne-Loccoz, P.; Incarvito, C.D.; Rheingold, A.L.; Kaderli, S.; Zuberbühler, A.D.; Karlin, K.D. “Tridentate Copper Ligand Influences on Heme-Peroxo-Copper Formation and Properties: Reduced, Superoxo, and μ-Peroxo Fe/Cu Complexes.” Inorg. Chem., 2005, 44, 7014-7029.
9. Kim, E.; Kamaraj, K.; Galliker, B.; Rubie, N.D.; Moënne-Loccoz, P.; Kaderli, S.; Zuberbühler, A.D.; Karlin, K.D. “Dioxygen Reactivity of Copper and Heme-Copper Complexes Possessing an Imidazole-Phenol Cross-Link.” Inorg. Chem., 2005, 44, 1238-1247.
8. Kim, E.; Shearer, J.; Lu, S.; Moënne-Loccoz, P.; Helton, M.E.; Kaderli, S.; Zuberbühler, A.D.; Karlin, K.D. “Heme/Cu/O2 Reactivity: Change in FeIII-(O22–)-CuII Unit Peroxo Binding Geometry Effected by Tridentate Copper Chelation.” J. Am. Chem Soc., 2004, 126, 12716-12717.
7. Kim, E.; Chufán, E.E.; Kamaraj, K.; Karlin, K.D. “Synthetic Models for Heme-Copper Oxidases.” Chem. Rev., 2004, 104, 1077-1133.
6. Karlin, K.D.; Kim, E. “Ligand influences in heme-copper O2-chemistry as synthetic models for cytochrome c oxidase.” Chem. Lett., 2004, 33, 1226-1231.
5. Kamaraj, K.; Kim, E.; Galliker, B.; Zakharov, L.N.; Rheingold, A.L.; Zuberbühler, A.D.; Karlin, K.D. “Copper(I) and Copper(II) Complexes Possessing Cross-Linked Imidazole-Phenol Ligands: Structures and Dioxygen Reactivity.” J. Am. Chem Soc., 2003, 125, 6028-6029.
4. Kim, E.; Helton, M.E.; Wasser, I.M.; Karlin, K.D.; Lu, S.; Huang, H-w.; Moënne-Loccoz, P.; Incarvito, C.D.; Rheingold, A.L.; Honecker, M.; Kaderli, S.; Zuberbühler, A.D. “Superoxo, μ-peroxo and μ-oxo complexes from heme/O2 and heme-Cu/O2 reactivity: Copper-ligand influences in cytochrome c oxidase models.” Proc. Natl. Acad. Sci. USA, 2003, 100, 3623-3628.
3. Zhang, C.X.; Liang, H.-C.; Kim, E.-i.; Shearer, J.; Helton, M.E.; Kim, E.; Kaderli, S.; Incarvito, C.D.,; Zuberbühler, A.D.; Rheingold, A.L.; Karlin, K.D. “Tuning Copper-Dioxygen Reactivity and Exogenous Substrate Oxidation via Alterations in Ligand Electronics” J. Am. Chem Soc., 2003, 125, 634-635.
2. Liang, H-C.; Kim, E.; Incarvito, C.D.; Rheingold, A.L.; Karlin, K.D. “A Bis-Acetonitrile Two-Coordinate Copper(I) Complex: Synthesis and Characterization of Highly soluble B(C6F5)4-Salts of [Cu(MeCN)2]+ and [Cu(MeCN)4]+.” Inorg. Chem., 2002, 41, 2209-2212.
1. Kim, E.; Lee, K-B.; Jang, H.G. “Dioxygen Binding to the Singly Alkoxo-Bridged Diferrous Complex: Properties of [FeII2(N-Et-HPTB)Cl2]BPh4.” Bull. Korean. Chem. Soc., 1996, 17, 1127-1131.